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Entrance Guru:Chemistry Model questions and answers part 1

Chemistry

1) In a multi -electron atom, which of the following orbitals described by the three quantum    numbers will have the same energy in the absence of magnetic and electric fields?

  i) n=1, l=0,m=0
  ii) n=2,l=0,m=0
  iii) n=2,l=1,m=1
  iv) n=3,l=2,m=1
  v) n=3,l=2,m=0

  a) (i)&(ii)
  b) (ii)&(iii)
  c) (iii)&(iv)
  d) (iv)&(v)

2) Which one of the following has the regular tetrahedral structure?
      (Atomic number B=5, S=16, Ni=28 ,Xe=54)

 a) XeF4
 b) SF4
 c) BF4-
 d) [Ni(CN)4]2-

3) The function of enzymes in the living system is to

 a) catalysis biochemical reactions
 b) provide energy
 c) transport oxygen
 d) provide immunity

4) Which of the following molecules/ions does not
 a) O22-
 b) B2
 c) N2
 d) O2

5) Aspirin is an acetylation product of 

 a) m-Hydroxybenzoic acid
 b) o-Dihydroxybenzene 
 c) o-Hydroxybenzoic acid
 d) p-Dihydroxybenzene 

Answers

1) d) (iv)&(v)  Orbitals having same (n + 1) value in the absence of electric and magnetic field will have same energy.

2) c)BF4- is regular tetrahedral

3) a) catalysis biochemical reactions The enzymes are globular proteins which catalyse chemical reactions in the living systems.

4) a) O22-

5) c) o-Hydroxybenzoic acid  Aspirin is acetyl salicylic acid,which is formed by acetylation of                                   o- Hydroxybenzoic acid


Entrance Guru:Physics Model questions and answers part 1


Physics
  • A wire 50 cm long and 1 mm^2  in cross section carries a current of 4 A when connected to a 2 V battery .The resistivity  of  the wire is                                                                                            a) 4 x 10^-6      b) 1 x 10^-6  c) 2 x 10^-7  d) 5 x 10^-7
  • The frequency of sinusodial wave     y = 0.4cos[2000 t + 0.80] would be                                             a) 1000 π Hz     b) 2000 Hz     c) 20 Hz        d) 1000/π Hz
  • The frequency of electromagnetic wave, which best suited to observe a particle of radius 3 x 10^-4 cm is of the order of                                                                                                                  a) 10^15            b) 10^14            c) 10^13          d) 10^12
  • Which rays contain (positive) charged particles?                                                                                   a) α-rays            b) β-rays        c) γ-rays          d)X-rays
    • Half life of a radioactive element is 12.5 hour and its quantity is 256 g.After how much time its quantity will remain 1 g?                                                                                                               a) 50 hrs           b) 100 hrs       c) 150 hrs        d) 200 hrs

                                                                       Answers 

    1) b)1 x 10^-6  { length l= 50 cm = 0.5 cm
                                Area A=1 mm^2 = 1x10^-6 m^2
                                Current I=4A and voltage V=2V
                                 Resistace R=V/I =2/4 =0.5
                                Risistivity ρ = R x A/l = (0.5 x 1x10^-6) / 0.5 = 1 x 10^-6)

    2) c) 1000/π hz { compare with equation y=acos(2πVt+φ)
                               this gives 2πV=1000/π Hz}

    3) b)10^14 { the wave length of radiation used should be less than the size of the particle size of           the particle                  =λ=C/ν
                     3 x 10^-4=(3x10^10)/ν or ν=10^14 Hz }

    4)a)  α-rays           { α rays are positively charged particles }

    5)b)100 hrs{N/N0 =(1/2)^n          n= number of decays                                                                                                    1/256=(1/2)^8 =(1/2)^n    where n=8   time for 8 half life=100 hrs

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